When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | HO2_LightfootJemi-Alade(1991)_298K_210-250nm.txt |
NAME: | hydroperoxy radical |
FORMULA: | HO2 |
AUTHOR(YEAR): | LightfootJemi-Alade(1991) |
T: | 298K |
λ: | 210-250nm |
BIBLIOGRAPHY: |
P.D. Lightfoot and A.A. Jemi-Alade, "The temperature dependence of the UV spectra of the HO2 and CH3O2 radicals",
J. Photochem. Photobiol A: Chem. 59, 1-10 (1991);
DOI: 10.1016/1010-6030(91)87062-Z
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COMMENTS: | Flash photolysis technique (Cl2/H2/O2 or Cl2/CH3OH/air mixtures) coupled with time resolved UV absorption spectrometry Data calibrated with σ(240 nm) = 4.55×10-18 cm2 molecule-1 for CH3O2 recommended by
F. Simon, W. Schneider, and G.K. Moortgat, "UV-absorption spectrum of the methylperoxy radical and the kinetics of its disproportionation reaction at 300 K", Int. J. Chem. Kinet. 22, 791-813 (1990) |
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